Scientists at the U.S. Department of Energy's National Renewable Energy Laboratory (NREL) reported significant advances in the thermoelectric performance of organic semiconductors based on carbon nanotube thin films that could be integrated into fabrics to convert waste heat into electricity or serve as a small power source.
Andrew Ferguson, a senior scientist in NREL’s Chemical and Materials Science and Technology center and co-lead author of the new Energy & Environmental Science paper, Large n- and p-type thermoelectric power factors from doped semiconducting single-walled carbon nanotube thin films, said the introduction of single-walled carbon nanotubes (SWCNT) into fabrics could serve an important function for "wearable" personal electronics. By capturing body heat and converting it into electricity, the semiconductor could power portable electronics or sensors embedded in clothing.
The research demonstrates significant potential for semiconducting single-walled carbon nanotubes (SWCNTs) as the primary material for efficient thermoelectric generators, rather than being used as a component in a composite thermoelectric material containing, for example, carbon nanotubes and a polymer.
“There are some inherent advantages to doing things this way,” said Jeffrey Blackburn, co-lead author of the paper with Ferguson and also a senior scientist in NREL’s Chemical and Materials Science and Technology center.
These advantages include the promise of solution-processed semiconductors that are lightweight and flexible and inexpensive to manufacture.
The paper revealed that removing polymers from all SWCNT starting materials served to boost the thermoelectric performance and lead to improvements in how charge carriers move through the semiconductor. The paper also demonstrated that the same SWCNT thin film achieved identical performance when doped with either positive or negative charge carriers. These two types of material--called the p-type and the n-type legs, respectively--are needed to generate sufficient power in a thermoelectric device. Semiconducting polymers, another heavily studied organic thermoelectric material, typically produce n-type materials that perform much worse than their p-type counterparts. The fact that SWCNT thin films can make p-type and n-type legs out of the same material with identical performance means that the electrical current in each leg is inherently balanced, which should simplify the fabrication of a device. The highest performing materials had performance metrics that exceed current state-of-the-art solution-processed semiconducting polymer organic thermoelectrics materials.
"We could actually fabricate the device from a single material," Ferguson said. "In traditional thermoelectric materials you have to take one piece that's p-type and one piece that's n-type and then assemble those into a device."